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Homo-metathesis of vinylsilanes catalysed by ruthenium carbene complexes
Authors:
- Cezary Pietraszuk,
- Bogdan Marciniec,
- Szymon Rogalski,
- Helmut Fischer
Abstract
Effective homo-metathesis of a series of dichloro-substituted vinylsilanes H2C = C(H)SiCl2R (where R = Me, OSiMe3, C 6H5, C6H4-Me-4, C6H 4-CF3-4) in the presence of second generation Grubbs catalyst [Cl2(PCy3)(IMesH2)Ru(=CHPh)] (I) and Hoveyda-Grubbs catalyst (II) leads to selective formation of E-1,2-bis(silyl)ethenes and ethene. On the basis of the results of experiments with deuterium-labelled reagents, a metallacarbene mechanism has been suggested for these reactions. © 2005 Elsevier B.V. All rights reserved.
- Record ID
- UAM00fa37bd4e48498585df77c2f57e0913
- Author
- Journal series
- Journal of Molecular Catalysis A-Chemical, ISSN 1381-1169
- Issue year
- 2005
- Vol
- 240
- Pages
- 67-71
- ASJC Classification
- ; ;
- DOI
- DOI:10.1016/j.molcata.2005.06.036 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 10; = 10; : 2014 = 1.431; : 2006 (2 years) = 2.511 - 2007 (5 years) =2.770
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM00fa37bd4e48498585df77c2f57e0913/
- URN
urn:amu-prod:UAM00fa37bd4e48498585df77c2f57e0913
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.