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Catalytic Activity of Rhodium-Siloxide Complexes in Hydrosilylation of Allyl Ethers and Allyl Esters
Authors:
- Bogdan Marciniec,
- Edyta Walczuk,
- Paulina Błazejewska-Chadyniak,
- Dariusz Chadyniak,
- Małgorzata Kujawa-Welten,
- Stanislaw Krompiec
Abstract
Rhodium-siloxide dimer [(diene)Rh(μ-OSiMe3)2] (I) appeared to be an active catalyst (even at room temperature) of the hydrosilylation of allyl ethers, CH2=CHCH2OR (R = CH2CHCH2O, C4H9, Ph, CH2Ph, (CH2CH2O)7H) by triethoxysilane and methylbis(trimethylsiloxy)silane as well as of allyl esters of selected carboxylic acids, i.e. allyl acetate and allyl butyrate, to yield the usual hydrosilylation products accompanied (in the case of ethers) by traces of dehydrogenative silylation products.
- Record ID
- UAM24b3092b4b084a1ca33b076d97fb1656
- Author
- Pages
- 415-419
- Book
- Organosilicon Chemistry Set: From Molecules to Materials, 2005, 415-419 p., ISBN 9783527323470
- DOI
- DOI:10.1002/9783527620777.ch67d Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 3
- Publication indicators
- = 0
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM24b3092b4b084a1ca33b076d97fb1656/
- URN
urn:amu-prod:UAM24b3092b4b084a1ca33b076d97fb1656
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