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Unusual reactivity of poly(trifluoromethyl)benzenes. Semiempirical reaction modelling
Authors:
- Henryk Koroniak,
- Piotr Fiedorow,
- Wojciech Dmowski,
- Jacek Porwisiak
Abstract
The reaction of methyllithium with 1,3,5-tris(trifluoromethyl)benzene, 1, 1,2,4,5-tetrakis(trifluoromethyl)benzene, 2, and 1,2,4-tris(trifluoromethyl)benzene, 3, was analyzed using the semiempirical package mopac 6. It was shown that formation of lithium-hydrogen exchange products are favoured only in the case of compound 1, whereas in the case of 2 and 3 the major products were those of nucleophilic substitution. © 1995, All rights reserved.
- Record ID
- UAM25c0f7e16d5f4ca9bd7d12e5e00d7f86
- Author
- Journal series
- Journal of Molecular Structure, ISSN 0022-2860
- Issue year
- 1995
- Vol
- 351
- Pages
- 187-195
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1016/0022-2860(94)08491-Y Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 3; = 3; : 1999 = 0.860; : 2006 (2 years) = 1.495 - 2007 (5 years) =1.497
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM25c0f7e16d5f4ca9bd7d12e5e00d7f86/
- URN
urn:amu-prod:UAM25c0f7e16d5f4ca9bd7d12e5e00d7f86
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.