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Intermolecular Li+ bonds between N-oxides with fluctuating Li+ ions: An FTIR study
Authors:
- Bogumił Brzezinski,
- Georg Zundel,
- Rainer Krämer
Abstract
In 2:1 LiClO4 trimethylamine-N-oxide and 4-methoxypyridine-N-oxide mixtures 2:1 Li+-N-oxide complexes are formed. If more N-oxide is present, 1: 2 complexes form. In the intermolecular O...Li+...O bonds the Li+ ions fluctuate in a broad flat single-minimum potential. These bonds show so-called Li+ polarizability as indicated by a continuum in the region below 250 cm-1. © 1988.
- Record ID
- UAM30a2dfde84a64a739203e669c1891269
- Author
- Journal series
- Chemical Physics Letters, ISSN 0009-2614
- Issue year
- 1988
- Vol
- 146
- Pages
- 138-142
- ASJC Classification
- ;
- DOI
- DOI:10.1016/0009-2614(88)85062-0 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 30
- Score source
- journalList
- Publication indicators
- = 12; : 1999 = 0.992; : 2006 (2 years) = 2.462 - 2007 (5 years) =2.392
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM30a2dfde84a64a739203e669c1891269/
- URN
urn:amu-prod:UAM30a2dfde84a64a739203e669c1891269
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.