Energy-resolved in-source collisionally induced dissociation for the evaluation of the relative stability of noncovalent complexes in the gas phase
Authors:
- Nataliya Lyapchenko,
- Grzegorz Marek Schroeder
Abstract
Energy-resolved in-source collisionally induced dissociation (CID) studies on the complexation of alkali metal cations by some crown ethers, nucleic acid bases, and amino acids have been performed. It has been shown that the cone voltage corresponding to the maximum ion abundance (Vc,Imax) of the breakdown curve is characteristic of a given ion and not influenced by the cone desolvation process or the composition of the solution. Very good agreement of the Vc,Imax value with the bond strength of the ion has been observed. Determination of the Vc,Imax values for different ionic species is a useful, simple, and inexpensive way to obtain their relative stabilities in insource CID conditions. Copyright © 2005 John Wiley & Sons, Ltd.
- Record ID
- UAM403e8b893337497dbe08bda396070623
- Author
- Journal series
- Rapid Communications in Mass Spectrometry, ISSN 0951-4198
- Issue year
- 2005
- Vol
- 19
- Pages
- 3517-3522
- ASJC Classification
- ; ;
- DOI
- DOI:10.1002/rcm.2212 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 4; = 4; = 9; : 2005 = 1.149; : 2006 (2 years) = 2.680 - 2007 (5 years) =3.011
- Citation count
- 9
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM403e8b893337497dbe08bda396070623/
- URN
urn:amu-prod:UAM403e8b893337497dbe08bda396070623
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.