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The oxidation of cyclic diols on a gold elecrode structure‐reactivity relationships
Authors:
- Teresa Renata Łuczak,
- Rudolf Holze,
- Maria Bełtowska-Brzezinska
Abstract
The electrooxidation of the three isomeric 1,2‐, 1,3‐, and 1,4‐cyclohexanediols at a gold electrode in contact win an alkaline electrolyte solutior has been studied with cyclic voltammetry. Signficant differences in the electrochemical activity of the isomers were found. The 1,2‐diol is by far the most active one. Its trans‐isomer is more reactive than the cis‐isomer. These differences are rationalized based on the molecular structure and the different elearosorption properties. Copyright © 1994 VCH Verlagsgesellschaft mbH
- Record ID
- UAM43119530496c4e0a9d68c794e2ccd976
- Author
- Journal series
- Electroanalysis, ISSN 1040-0397
- Issue year
- 1994
- Vol
- 6
- Pages
- 773-778
- ASJC Classification
- ;
- DOI
- DOI:10.1002/elan.1140060911 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 8; = 10; : 1999 = 0.927; : 2006 (2 years) = 2.444 - 2007 (5 years) =2.923
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM43119530496c4e0a9d68c794e2ccd976/
- URN
urn:amu-prod:UAM43119530496c4e0a9d68c794e2ccd976
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.