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The free-radical addition of phenyl trichloromethyl selenide to alkenes: A new method for the regioselective carboxylation of alkenes
Authors:
- Thomas G. Back,
- Kazimierz Minksztym
Abstract
The free-radical addition of phenyl trichloromethyl selenide to alkenes affords 2-phenylseleno-1-trichloromethylalkanes, which can be converted into α,β-unsaturated carboxylic acids or amides by base-promoted dehydrochlorination, followed by [2,3]sigmatropic rearrangement of the corresponding selenoxides in the presence of water or diethylamine, respectively.
- Record ID
- UAM4867645154744d6e875143061edaeacc
- Author
- Journal series
- Chemical Communications, ISSN 1359-7345
- Issue year
- 1997
- Pages
- 1759-1760
- ASJC Classification
- ; ; ; ; ; ;
- DOI
- DOI:10.1039/a704153e opening in a new tab
- Language
- en English
- Score (nominal)
- 40
- Score source
- journalList
- Publication indicators
- = 4; : 1999 = 1.204; : 2006 = 4.521 (2) - 2007=4.645 (5)
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM4867645154744d6e875143061edaeacc/
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perishopening in a new tab system.