Synthesis and properties of cyanosilicone stationary phases for capillary complexation gas chromatography
Authors:
- Rafał Tomasz Wawrzyniak,
- Wiesław Wasiak
Abstract
The synthesis of liquid stationary phases with cyanopropylmethyl polysiloxane containing cations of Cu2+ Or Co2+ which were bonded to the resulting polymer via cyano groups is described. Columns of 30 m x 0.53 mm were coated with these stationary phases (film thickness of 0.5 μm.). The characteristics of the polysiloxanes obtained were determined by the use of spectroscopic techniques (UV-vis,IR). The thermal stability of the columns was established and the average molecular mass of the polymer was calculated. The Grob test mixture was also used to evaluate the columns.
- Record ID
- UAM596027c2ca814004b8c54662164153a1
- Author
- Journal series
- Chromatographia, ISSN 0009-5893
- Issue year
- 1997
- Vol
- 46
- Pages
- 593-598
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1007/BF02490518 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 5; = 5; : 1999 = 1.034; : 2006 (2 years) = 1.171 - 2007 (5 years) =1.051
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM596027c2ca814004b8c54662164153a1/
- URN
urn:amu-prod:UAM596027c2ca814004b8c54662164153a1
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.