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Subtleties in asymmetric catalyst structure: The resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis
Authors:
- Jonathan Hopewell,
- Piotr Jankowski,
- Claire L. McMullin,
- A. Guy Orpen,
- Paul G. Pringle
Abstract
An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine β-CgPH is an active and moderately selective asymmetric hydrogenation catalyst. © 2010 The Royal Society of Chemistry.
- Record ID
- UAM5f9a3b6423114862bbb9b0526a9e72b2
- Author
- Journal series
- Chemical Communications, ISSN 1359-7345
- Issue year
- 2010
- Vol
- 46
- Pages
- 100-102
- Publication size in sheets
- 0.30
- ASJC Classification
- ; ; ; ; ; ;
- DOI
- DOI:10.1039/b916359j Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 19; = 21; : 2010 = 1.260; : 2010 (2 years) = 5.787 - 2010 (5 years) =5.582
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM5f9a3b6423114862bbb9b0526a9e72b2/
- URN
urn:amu-prod:UAM5f9a3b6423114862bbb9b0526a9e72b2
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.