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A facile synthesis of 1,1-bis(silyl)ethenes
Authors:
- Piotr Pawluć,
- Bogdan Marciniec,
- Grzegorz Hreczycho,
- Beata Gaczewska,
- Yujiro Itami
Abstract
(Chemical Equation Presented). Symmetrical 1,1-bis(silyl)ethenes have been easily prepared via ruthenium complex-catalyzed silylative coupling cyclization of 1,2-bis(dimethylvinylsiloxy)ethane to give 2,2,4,4-tetramethyl-3-methylene-1, 5-dioxa-2,4-disilacycloheptane with excellent selectivity and good yield, followed by its reaction with Grignard reagents. The cyclic product can also be effectively transformed into cyclic carbosiloxane, 2,2,4,4,6,6,8,8-octamethyl-3, 7-dimethylene-1,5-dioxa-2,4,6,8-tetrasilacyclooctane.
- Record ID
- UAM615b68c784f04b00bce5cb404e9208d3
- Author
- Journal series
- Journal of Organic Chemistry, ISSN 0022-3263
- Issue year
- 2005
- Vol
- 70
- Pages
- 370-372
- ASJC Classification
- DOI
- DOI:10.1021/jo048784c Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 23; = 22; = 28; : 2005 = 1.281; : 2006 (2 years) = 3.790 - 2007 (5 years) =3.716
- Citation count
- 28
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM615b68c784f04b00bce5cb404e9208d3/
- URN
urn:amu-prod:UAM615b68c784f04b00bce5cb404e9208d3
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.