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Self-assembly of a covalent organic cage with exceptionally large and symmetrical interior cavity: The role of entropy of symmetry
Authors:
- Paweł Skowronek,
- Beata Irena Warżajtis,
- Urszula Rychlewska,
- Jacek Gawroński
Abstract
An exceptionally large size cuboctahedral imine cage is obtained from small size organic molecules in a thermodynamically driven [8+12] cyclocondensation. This is a demonstration of the role of entropy of symmetry as a driving force in reversible reactions. © 2013 The Royal Society of Chemistry.
- Record ID
- UAM65c3543acfaa43819ddf81dbc1388a3e
- Author
- Journal series
- Chemical Communications, ISSN 1359-7345
- Issue year
- 2013
- Vol
- 49
- Pages
- 2524-2526
- ASJC Classification
- ; ; ; ; ; ;
- DOI
- DOI:10.1039/c3cc39098e Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 40
- Score source
- journalList
- Score
- Publication indicators
- = 62; = 57; : 2013 = 1.367; : 2013 (2 years) = 6.718 - 2013 (5 years) =6.485
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM65c3543acfaa43819ddf81dbc1388a3e/
- URN
urn:amu-prod:UAM65c3543acfaa43819ddf81dbc1388a3e
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.