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Kinetics and mechanism of reactions between tetranitrodibenzo crown ethers and alkali metal hydroxides
Authors:
- Grzegorz Marek Schroeder,
- Bogusława Łęska
Abstract
The paper reports results of the kinetic and spectroscopic studies of reactions between tetranitrodibenzo crown ethers: TNDB 18C6, TNDB 24C8 and TNDB 30C10 or theirs analogs: 1,2-dimethoxy-or 1,2-diethoxybenzenes and alkali metal hydroxides: LiOH, NaOH, KOH, RbOH and CsOH in DMSO: water (95:5 v/v) mixture. These reactions lead via the non-concerted mechanism to formation of σ-adducts and complexes with metal cations.
- Record ID
- UAM729a9a9037374b7ab8909b442bc4971b
- Author
- Journal series
- Supramolecular Chemistry, ISSN 1061-0278
- Issue year
- 1997
- Vol
- 9
- Pages
- 17-24
- ASJC Classification
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 2; = 1; : 2014 = 0.467; : 2006 (2 years) = 1.861 - 2007 (5 years) =1.517
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM729a9a9037374b7ab8909b442bc4971b/
- URN
urn:amu-prod:UAM729a9a9037374b7ab8909b442bc4971b
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