Cross-coupling of vinyldisilacyclobutane with olefins catalyzed by [RuH(Cl)(CO)(PCy<inf>3</inf>)<inf>2</inf>]

Jankowska-Wajda, Magdalena; Shuvalova, Olga; Bespalova, Natalia; Majchrzak, Mariusz Paweł; Marciniec, Bogdan

doi:10.1016/j.jorganchem.2005.01.036

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Cross-coupling of vinyldisilacyclobutane with olefins catalyzed by [RuH(Cl)(CO)(PCy3)2]

Authors:

Magdalena Jankowska-Wajda,
Olga Shuvalova,
Natalia Bespalova,
Mariusz Paweł Majchrzak,
Bogdan Marciniec

Abstract

Cross-coupling of vinyldisilacyclobutane with a variety of olefins in the presence of [RuH(Cl)(CO)(PCy₃)₂] leads to stereoselective formation of functionalized vinyldisilacyclobutanes. Analogous homo-coupling of vinyldisilacyclobutane leads to the formation of E- and gem-bis(silyl)ethenes. The reaction offers a new route for synthesis of attractive monomers for ring opening polymerization (ROP). © 2005 Elsevier B.V. All rights reserved.

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Record ID: UAM7ac7210449fa4a33993db39dd8a771a5
Author: Magdalena Jankowska-Wajda Magdalena Jankowska-Wajda,, Zakład Chemii i Technologii Związków Krzemu [nowa struktura organizacyjna] (SNŚ/WC/JWC)Szkoła Nauk Ścisłych [nowa struktura organizacyjna] (SNŚ)
Olga Shuvalova Olga Shuvalova,, External affiliation of publication: A.V.Topchiev Institute of Petrochemical Synthesis, RAS
Natalia Bespalova Natalia Bespalova,, External affiliation of publication: A.V.Topchiev Institute of Petrochemical Synthesis, RAS
Mariusz Paweł Majchrzak Mariusz Paweł Majchrzak,, Zakład Chemii Metaloorganicznej [nowa struktura organizacyjna] (SNŚ/WC/JWC)Szkoła Nauk Ścisłych [nowa struktura organizacyjna] (SNŚ)
Bogdan Marciniec Bogdan Marciniec,, Centrum Zaawansowanych Technologii (Cb/CZT)Centra badawcze [nowa struktura organizacyjna] (Cb)
Journal series: Journal of Organometallic Chemistry, ISSN 0022-328X
Issue year: 2005
Vol: 690
Pages: 4492-4497
ASJC Classification: 2505 Materials Chemistry; 1604 Inorganic Chemistry; 1605 Organic Chemistry; 1606 Physical and Theoretical Chemistry; 1303 Biochemistry
DOI: DOI:10.1016/j.jorganchem.2005.01.036 Opening in a new tab
Language: (en) English
Score (nominal): 0
Score source: journalList
Publication indicators: Scopus Citations = 11; WoS Citations = 10; GS Citations = 12; Scopus SNIP: 2005 = 0.848; WoS Impact Factor: 2006 (2 years) = 2.332 - 2007 (5 years) =2.097
Citation count: 1

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Uniform Resource Identifier: https://researchportal.amu.edu.pl/info/article/UAM7ac7210449fa4a33993db39dd8a771a5/

URN: urn:amu-prod:UAM7ac7210449fa4a33993db39dd8a771a5

* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.