Back
Nonequilibrium, diffusional effects on reversible dissociation of excited acids
Authors:
- Andrzej Molski
Abstract
The statistical nonequilibrium thermodynamic theory of rapid reactions is used to study reversible dissociation of acids in the excited state. A relation involving nonequilibrium, diffusional effects is demonstrated between the steady-state reaction quotient Qss and the corresponding intrinsic equilibrium) excited acid dissociation constant K*. Explicit expressions are derived for the molecular protonation rate coefficients describing the steady-state and frequency domain kinetics. © 1994.
- Record ID
- UAM958e5e6163a74bb18726691ac8d1b39f
- Author
- Journal series
- Chemical Physics Letters, ISSN 0009-2614
- Issue year
- 1994
- Vol
- 226
- Pages
- 37-46
- ASJC Classification
- ;
- DOI
- DOI:10.1016/0009-2614(94)00696-2 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 2; = 1; : 1999 = 0.992; : 2006 (2 years) = 2.462 - 2007 (5 years) =2.392
Share
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM958e5e6163a74bb18726691ac8d1b39f/
- URN
urn:amu-prod:UAM958e5e6163a74bb18726691ac8d1b39f
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.