Crystal and molecular structure of 15-oxosparteine-N(1)-oxide perchlorate
Authors:
- Andrzej Katrusiak,
- Z. Kałuski
Abstract
[C15H25N2O2+·ClO4-, Mr=364.83, is monoclinic:P21, a=7.885(1), b=10.685(1), c=10.658(1) Å, β=105.63(1)°, Vc=864.8(2) Å3, Z=2, Dx=1.39(1)g cm-3, λ(Cu Kα)=1.54178 Å, μ(Cu Kα)=21.4 cm-1, F(000)=388 e, T=292K, R=0.066 for 1205 unique reflections. The piperidine rings A, B, C, and D have chair, chair, boat, and half-chair conformations, respectively. The quinolizidine system (rings A/B) has a trans configuration. The cations are interconnected by a hydrogen bond O(N1)⋯O(C15) of 2.552(10) Å into chains along [010]. Atoms C(12) and C(13) from ring D of the cation are disordered. Very high thermal parameters of the oxygen atoms of the perchlorate anion may indicate its orientational disorder. © 1988 Plenum Publishing Corporation.
- Record ID
- UAM9766a604ff7f41d9851e892621a88f72
- Author
- Journal series
- Journal of Crystal and Molecular Structure, ISSN 0308-4086, e-ISSN 1572-8854
- Issue year
- 1988
- Vol
- 18
- Pages
- 365-373
- ASJC Classification
- ; ;
- DOI
- DOI:10.1007/BF01195689 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 4; = 6; = 5
- Citation count
- 5
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAM9766a604ff7f41d9851e892621a88f72/
- URN
urn:amu-prod:UAM9766a604ff7f41d9851e892621a88f72
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.