Simultaneous introduction of trifluoromethyl and λ&lt;sup&gt;6&lt;/sup&gt;-pentafluorosulfanyl substituents using F&lt;inf&gt;5&lt;/inf&gt;S-CC-CF&lt;inf&gt;3&lt;/inf&gt; as a dienophile

Duda, Błażej; Lentz, Dieter

doi:10.1039/c5ob00610d

Back

Simultaneous introduction of trifluoromethyl and λ<sup>6</sup>-pentafluorosulfanyl substituents using F<inf>5</inf>S-CC-CF<inf>3</inf> as a dienophile

Authors:

Błażej Duda,
Dieter Lentz

Abstract

F5S-CC-CF3 can be easily prepared in high yields in two steps from 3,3,3-trifluoropropyne. It is a powerful, versatile dienophile in Diels-Alder reactions. Reactions at room temperature provide the corresponding products in up to quantitative yields allowing the introduction of the pentafluorosulfanyl group and trifluoromethyl group at the 1,2 position.

Metrics

Record ID

UAM9f7d7d9548a14f55a31d2b002275bef4

Author

Błażej Duda

Dieter Lentz

Journal series

Organic & Biomolecular Chemistry, ISSN 1477-0520

Issue year

2015

Vol

13

Pages

5625-5628

ASJC Classification

1605 Organic Chemistry; 1606 Physical and Theoretical Chemistry; 1303 Biochemistry

DOI

DOI:10.1039/c5ob00610d

Language

(en) English

Score (nominal)

35

Score source

journalList

Score

Publication indicators

Scopus Citations = 10; Scopus SNIP: 2015 = 0.850; WoS Impact Factor: 2015 (2 years) = 3.559 - 2015 (5 years) =3.367

Cite

Share via portal AddThis

Uniform Resource Identifier: https://researchportal.amu.edu.pl/info/article/UAM9f7d7d9548a14f55a31d2b002275bef4/

URN: urn:amu-prod:UAM9f7d7d9548a14f55a31d2b002275bef4

* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.