Photochemistry of 4-(methylthio)phenylacetic acid. Steady-state and laser flash photolysis studies

Authors:

• Piotr Filipiak,
• Gordon L. Hug,
• Krzysztof Bobrowski,
• Bronisław Marciniak

Abstract

The mechanism for the direct photolysis of 4-(methylthio)phenylacetic acid (4-MTPA) in acetonitrile was investigated using steady-state and laser flash photolysis. A variety of primary stable photoproducts was found under steady-state, 254 nm irradiation of acetonitrile solutions including carbon dioxide (photodecarboxylation), phenylacetic acid, dimethyl disulfide, methyl p-tolyl sulfide, 4-(methylthio)benzaldehyde, 4-(methylthio)benzyl alcohol and secondary stable photoproducts including toluene, benzyl alcohol, benzaldehyde, 1,2-diphenylethane. These stable photoproducts were identified and characterized using HPLC, GC, GC-MS, and UV-Vis methods. Quantum yields were determined for the formation of the various stable products in steady-state irradiations in the absence and in the presence of oxygen. Following laser flash photolysis (266 nm Nd:YAG laser) a variety of transients (e.g., the 4-MTPA triplet state and the sulfur-centered radical cation, H ₃C-S_•+-C₆H₄-CH ₂ COOH) was found. A detailed mechanism of the primary and secondary processes is proposed and discussed. The photoinduced C-C bond cleavages are shown to result from an excited-singlet reaction pathway, and the C-S bond cleavages follow a triplet pathway. The validity of this proposed mechanism was supported by an analysis of the quantum yields of stable products and their transient precursors. The results from excited-state quenching by oxygen are also consistent with the proposed mechanism. © 2004 Elsevier B.V. All rights reserved.