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Vinyl- and chloromethyl-substituted mono-T8 and double-decker silsesquioxanes as specific cores to low generation dendritic systems
Authors:
- Aleksandra Anna Mrzygłód,
- Maciej Kubicki,
- Beata Dudziec
- Record ID
- UAMad7052b5732c44f8b81a46fdf44887a9
- Author
- Journal series
- Dalton Transactions, ISSN 1477-9226, e-ISSN 1477-9234
- Issue year
- 2022
- Vol
- 51
- No
- 3
- Pages
- 1144-1149
- ASJC Classification
- Abstract in original language
- We report the series of G1 and G1.5 dendritic systems with mono-T8 SQs and DDSQ as specific types of dendron and dendrimer cores, respectively. The trivinyl- and tri(chloromethyl)-derivatives were obtained via hydrolytic condensation followed by the hydrosilylation reaction, optimized to yield selectively β-products. Their structures were confirmed by spectroscopic and XRD analyses. It is the first example of double-decker SQs used as cores for the construction of a low generation of dendrimer featuring specific dumbbell frameworks expanding in two or four directions
- DOI
- DOI:10.1039/d1dt04012j Opening in a new tab
- URL
- https://pubs.rsc.org/en/content/articlelanding/2022/DT/D1DT04012J Opening in a new tab
- Language
- eng (en) English
- License
- Score (nominal)
- 140
- Score source
- journalList
- Score
- = 140.0, 14-05-2022, ArticleFromJournal
- Publication indicators
- = 0; : 2018 = 0.900; : 2019 (2 years) = 4.174 - 2019 (5 years) =3.812
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMad7052b5732c44f8b81a46fdf44887a9/
- URN
urn:amu-prod:UAMad7052b5732c44f8b81a46fdf44887a9
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.