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The role of cations in the reaction between alcohols and hydrogen sulfide on x-type
Authors:
- Maria Ziółek,
- D. Szuba,
- R. Leksowski
Abstract
The reaction of methanol and ethanol with hydrogen sulfide was carried out over alkali cation-exchanged X-type zeolites. The yield of thiols decreases with the increase in the zeolites electronegativity. Alkali cations play the role of active sites in two different manners: if as agents leading to the formation of acidic OH groups by the dissociation of H2O and H2S, and ii/ as places for the adsorption of alcohols and hydrogen sulfide. © Elsevier Science Publishers B.V.
- Record ID
- UAMb118bfb5d32e4efda8083df9ff9c2a8e
- Author
- Pages
- 427-434
- Book
- Studies in Surface Science and Catalysis, Studies in Surface Science and Catalysis, 1988, 427-434 p.
- ASJC Classification
- ; ; ; ;
- DOI
- DOI:10.1016/S0167-2991(09)60619-4 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 3
- Publication indicators
- = 10; : 1999 = 0.676
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMb118bfb5d32e4efda8083df9ff9c2a8e/
- URN
urn:amu-prod:UAMb118bfb5d32e4efda8083df9ff9c2a8e
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.