Investigation of the electronic structure of SnCl4 L2 , TiCl4 L2 and SbCl5 L complexes by X-ray fluorescence spectroscopy
Authors:
- O.Kh. Poleshchuk,
- Boleslaw Nogaj,
- Jerzy Kasprzak,
- Jacek Koput,
- G.N. Dolenko,
- V.P. Elin,
- A.L. Ivanovskii
Abstract
The electronic structure of SbCl5L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl4L2 and TiCl4L2 complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom. © 1994.
- Record ID
- UAMc2e3beabb9e1497080aac4db9f43bdf1
- Author
- Journal series
- Journal of Molecular Structure, ISSN 0022-2860
- Issue year
- 1994
- Vol
- 324
- Pages
- 215-222
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1016/0022-2860(94)08316-9 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 12; = 8; : 1999 = 0.860; : 2006 (2 years) = 1.495 - 2007 (5 years) =1.497
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMc2e3beabb9e1497080aac4db9f43bdf1/
- URN
urn:amu-prod:UAMc2e3beabb9e1497080aac4db9f43bdf1
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.