Investigation of the electronic structure of SnCl<inf>4</inf>L<inf>2</inf>, TiCl<inf>4</inf>L<inf>2</inf> and SbCl<inf>5</inf>L complexes by X-ray fluorescence spectroscopy

Poleshchuk, O.Kh.; Nogaj, Boleslaw; Kasprzak, Jerzy; Koput, Jacek; Dolenko, G.N.; Elin, V.P.; Ivanovskii, A.L.

doi:10.1016/0022-2860(94)08316-9

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Investigation of the electronic structure of SnCl4L2, TiCl4L2 and SbCl5L complexes by X-ray fluorescence spectroscopy

Authors:

O.Kh. Poleshchuk,
Boleslaw Nogaj,
Jerzy Kasprzak,
Jacek Koput,
G.N. Dolenko,
V.P. Elin,
A.L. Ivanovskii

Abstract

The electronic structure of SbCl₅L complexes has been analyzed on the basis of the fluorescence spectra of the sulfur and chlorine atoms as well as quantum chemical XαDV and PM3 calculations. The results have been compared with the corresponding data for SnCl₄L₂ and TiCl₄L₂ complexes. An increase in electron density on the chlorine atoms accompanied by a decrease on the central metal atom has been observed for the complexes arranged according to their stability. The arrangement of Sn, Sb, and Ti complexes with dimethyl sulfide according to their increasing stability is in disagreement with the order of the complexes with respect to electron density on the sulfur atom. © 1994.

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Record ID: UAMc2e3beabb9e1497080aac4db9f43bdf1
Author: O.Kh. Poleshchuk O.Kh. Poleshchuk,, External affiliation of publication: Uniwersytet im. Adama Mickiewicza w Poznaniu, Boleslaw Nogaj Boleslaw Nogaj,, , Jerzy Kasprzak Jerzy Kasprzak,, , Jacek Koput Jacek Koput,, , G.N. Dolenko G.N. Dolenko,, External affiliation of publication: AE Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, V.P. Elin V.P. Elin,, External affiliation of publication: AE Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, A.L. Ivanovskii A.L. Ivanovskii,, External affiliation of publication: Russian Academy of Sciences
Journal series: Journal of Molecular Structure, ISSN 0022-2860
Issue year: 1994
Vol: 324
Pages: 215-222
ASJC Classification: 1604 Inorganic Chemistry; 1605 Organic Chemistry; 1607 Spectroscopy; 1602 Analytical Chemistry
DOI: DOI:10.1016/0022-2860(94)08316-9 opening in a new tab
Language: en English
Score (nominal): 20
Score source: journalList
Publication indicators: Scopus Citations = 12.000; Scopus SNIP: 1999 = 0.860; WoS Impact Factor: 2006 = 1.495 (2) - 2007=1.497 (5)

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