Interactions of trialkoxysilanes with some organic solvents
Authors:
- Bogdan Marciniec,
- Hanna Gulińska
Abstract
Changes in proton chemical shift δ (downfield) for the hydrogen bonded directly to the silicon atom of the trialkoxysilanes (RO)3SiH (where R CH3, C2H5, C3H7, iso-C3H7) in several, mainly aromatic, solvents as well as changes in δ(CH) of the aromatic ring (downfield), δ (CH) of chloroform (downfield) and in δ(CH) of the alkoxy groups (in aromatic solvent upfield, in CHCl3 downfield) were observed for the trialkoxysilane-aromatic (and CHCl3) solvent systems. The results obtained are interpreted mainly in terms of interaction of SiOC bonds in trialkoxysilane with organic solvent molecules, particularly for n-electrons of the alkoxy groups, with the benzene ring functioning as a π-electron acceptor (and with protonic hydrogen of chloroform). © 1982.
- Record ID
- UAMc32b319f9d344d168c83cb3e0e839a39
- Author
- Journal series
- Journal of Organometallic Chemistry, ISSN 0022-328X
- Issue year
- 1982
- Vol
- 236
- Pages
- 1-5
- ASJC Classification
- ; ; ; ;
- DOI
- DOI:10.1016/S0022-328X(00)86744-3 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 3; = 4; : 1999 = 0.766; : 2006 (2 years) = 2.332 - 2007 (5 years) =2.097
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMc32b319f9d344d168c83cb3e0e839a39/
- URN
urn:amu-prod:UAMc32b319f9d344d168c83cb3e0e839a39
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.