The relation between the nonlinear dielectric effect and solvent polarity
Authors:
- Maria Dutkiewicz,
- Grzegorz Edward Dutkiewicz
Abstract
The relation between solvent polarity expressed through the Dimroth-Reichardt spectroscopic parameter ET(30) and the nonlinear dielectric effect (NDE) expressed through the parameter Δε/E2 is demonstrated where Δε is a change in the electric permittivity ε of a solvent in an external strong electric field E. Both ET(20) and Δε/E2, determined in quite different ways, are extremely sensitive to the dielectric properties of a solvent which depend on molecular interactions. Linear correlations between Δε/E2 and ET(30) have been found for n-alkanols representing hydrogenbond donor solvents, and for halogenobenzenes which are dipolar, aprotic, weakly-associated solvents. © 1993 Plenum Publishing Corporation.
- Record ID
- UAMcad932fb28794e6096720ca6738e354a
- Author
- Journal series
- Journal of Solution Chemistry, ISSN 0095-9782
- Issue year
- 1993
- Vol
- 22
- Pages
- 787-795
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1007/BF00648582 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 7; = 9; : 1999 = 0.947; : 2006 (2 years) = 1.026 - 2007 (5 years) =1.212
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMcad932fb28794e6096720ca6738e354a/
- URN
urn:amu-prod:UAMcad932fb28794e6096720ca6738e354a
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.