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The reaction heats and PM5 semiempirical studies of complexes formed between silicon podand and Li+ cations
Authors:
- Bogusława Łęska,
- Piotr Przybylski,
- Joanna Kurczewska,
- Bogumił Brzezinski,
- Grzegorz Marek Schroeder,
- Volodimir Rybachenko
Abstract
The complexation reaction of Li+ cations by silicon podands (1-12) was studied by calorimetric and PM5 semiempirical methods. Both methods provide evidence for formation of the respective complexes with Li+ cations of different stoichiometry. For compounds 1, 2, 4, 6 and 10 only formation of 1:1 complexes were observed whereas for compounds with longer oxaalkyl chains the formation of 1:x (x>1) complexes have been found. The structures of the complexes are visualised and discussed. © 2005 Elsevier B.V. All rights reserved.
- Record ID
- UAMcbbd285b272348f39b271cf0e9d1e352
- Author
- Journal series
- Journal of Molecular Structure, ISSN 0022-2860, e-ISSN 1872-8014
- Issue year
- 2005
- Vol
- 741
- No
- 1-3
- Pages
- 11-17
- Publication size in sheets
- 0.50
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1016/j.molstruc.2005.01.045 Opening in a new tab
- URL
- https://www.sciencedirect.com/science/article/abs/pii/S0022286005001195 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 10; = 11; : 2005 = 0.843; : 2006 (2 years) = 1.495 - 2007 (5 years) =1.497
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMcbbd285b272348f39b271cf0e9d1e352/
- URN
urn:amu-prod:UAMcbbd285b272348f39b271cf0e9d1e352
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.