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Critical phenomena in rotational spectra of an asymmetric triatomic molecule
Authors:
- Jan Makarewicz
Abstract
The rovibrational dynamics of a highly excited asymmetric triatomic molecule have been investigated using semiclassical and quantum mechanical methods. The rotational energy surface (RES) has been calculated exactly from the rigid-bender model of the molecule. The RES topology has been studied and the bifurcation of its critical points has been found at a certain critical value of the angular momentum. A reorganization of the energy level structure, due to a change of the RES topology, has been revealed. © 1997 Taylor & Francis Group, LLC.
- Record ID
- UAMce0b55125e3a450eb0efbaf2e3a0e2e6
- Author
- Journal series
- Molecular Physics, ISSN 0026-8976
- Issue year
- 1997
- Vol
- 91
- Pages
- 229-234
- ASJC Classification
- ; ; ;
- DOI
- DOI:10.1080/002689797171544 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 1; : 1999 = 0.928; : 2006 (2 years) = 1.690 - 2007 (5 years) =1.481
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMce0b55125e3a450eb0efbaf2e3a0e2e6/
- URN
urn:amu-prod:UAMce0b55125e3a450eb0efbaf2e3a0e2e6
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.