Melting behavior of bromobenzene within carbon nanotubes
Authors:
- Małgorzata Śliwińska-Bartkowiak,
- Monika Jażdżewska,
- Keith E. Gubbins,
- Liangliang Huang
Abstract
We report experimental results on the melting behavior of a dipolar substance, bromobenzene, adsorbed in multiwalled carbon nanotubes (MWNTs) of (2.4, 4.0, and 10) nm inner diameter. Dielectric relaxation spectroscopy (DRS) and differential scanning calorimetry (DSC) methods have been used to show a solid-liquid transition of confined C6H5Br. The C 6H5Br melting point in pores has been found to increase with decreasing pore diameter. This result is in qualitative agreement with that obtained in molecular simulation for CCl4 in similar MWNTs, where the adsorbate-wall interactions are strong compared to the adsorbate-adsorbate interactions (see Jazdzewska et al., Phys. Chem. Chem. Phys. 2005, 7, 3884-3887). © 2010 American Chemical Society.
- Record ID
- UAMe257d6096adf424f8f45f2f41f95ecba
- Author
- Journal series
- Journal of Chemical and Engineering Data, ISSN 0021-9568
- Issue year
- 2010
- Vol
- 55
- Pages
- 4183-4189
- Publication size in sheets
- 0.50
- ASJC Classification
- ;
- DOI
- DOI:10.1021/je1002576 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 15; = 13; : 2010 = 1.308; : 2010 (2 years) = 2.089 - 2010 (5 years) =2.298
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMe257d6096adf424f8f45f2f41f95ecba/
- URN
urn:amu-prod:UAMe257d6096adf424f8f45f2f41f95ecba
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.