Elastic behavior of the carbon tetrabromide clathrate of hexakis(phenylthio)benzene as determined by brillouin spectroscopy
Authors:
- Darek Michalski,
- Bogusław Mróz,
- Harry Kiefte,
- Mary Anne White,
- Maynard J. Clouter
Abstract
Brillouin scattering measurements have been carried out at room temperature on the CBr4 clathrate of hexakis-(phenylthio)benzene. This material crystallizes in the R3 space group (trigonal system), with a host:guest mole ratio of 1:2. The values of all seven adiabatic elastic constants were determined. The material is elastically more anisotropic than the previously investigated ethanol-Dianin's compound clathrate which has the same space group, yet the bulk modulus and the linear compressibilities of these materials are similar. These investigations reveal that noncentral forces act in the CBr4-HPTB crystal; these elastic properties may significantly affect other properties such as thermal conductivity. © 1993 American Chemical Society.
- Record ID
- UAMee979f86d36c4deb91b97734f4b2610f
- Author
- Journal series
- Journal of Physical Chemistry, ISSN 0022-3654
- Issue year
- 1993
- Vol
- 97
- Pages
- 12949-12953
- ASJC Classification
- ;
- DOI
- DOI:10.1021/j100151a050 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 4; = 4; : 1999 = 2.481
- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMee979f86d36c4deb91b97734f4b2610f/
- URN
urn:amu-prod:UAMee979f86d36c4deb91b97734f4b2610f
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.