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The effect of fluorine substituents on the structure of cyclopropane. The structure of 4,4,8,8-tetraf1uorotricyclo-(5.1.0.0.3,5) octane
Authors:
- William R. Dolbier Jr.,
- Maria Odaniec,
- Ewa Gomulka,
- Mariusz Jaskólski,
- Henryk Koroniak
Abstract
The first x-ray structure determination of a fluorine-substituted cyclopropane is reported. The title compound was synthesized via bis difluorocarbene addition to 1,4-cyc1ohexadiene and its structure determined via x-ray crystallographic techniques. Its cyclopropane bondlengths (1.552 and 1.452) are very similar to those reported earlier in a microwave study of the parent 1,1-difluorocyclopropane, while its cyclohexane ring is virtually planar. © 1984.
- Record ID
- UAMf634320a56254fdd947592340e671458
- Author
- Journal series
- Tetrahedron, ISSN 0040-4020
- Issue year
- 1984
- Vol
- 40
- Pages
- 3945-3948
- ASJC Classification
- ; ;
- DOI
- DOI:10.1016/0040-4020(84)85071-1 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 5; = 8; : 2014 = 0.905; : 2006 (2 years) = 2.817 - 2007 (5 years) =2.854
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMf634320a56254fdd947592340e671458/
- URN
urn:amu-prod:UAMf634320a56254fdd947592340e671458
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.