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Acyclic diene metathesis (ADMET) oligomerization of divinyltetramethyldisiloxane in the presence of rhodium and ruthenium complexes
Authors:
- Bogdan Marciniec,
- Mariusz Lewandowski
Abstract
Acyclic diene metathesis (ADMET) polymerization of divinyltetramethyldisiloxane in the presence of rhodium [RhCl(COD)]2 and ruthenium RuCl2(PPh3)3 catalysts led predominantly to linear oligomers [Mn=1815, Mw/Mn=1.16] if the rhodium catalyst was used or to mixtures of dimeric and trimeric oligomers if the ruthenium complex was applied. The rhodium complex appeared to be the first effective catalyst for ADMET polymerization of divinyldisubstituted organosilicon compounds. © 1995 Plenum Publishing Corporation.
- Record ID
- UAMf64d6ac7d0df4fe7a0d543c6c9352e7d
- Author
- Journal series
- Journal of Inorganic and Organometallic Polymers, ISSN 1053-0495, e-ISSN 1572-8870
- Issue year
- 1995
- Vol
- 5
- Pages
- 115-122
- ASJC Classification
- ;
- DOI
- DOI:10.1007/BF01058140 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 25; = 28
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMf64d6ac7d0df4fe7a0d543c6c9352e7d/
- URN
urn:amu-prod:UAMf64d6ac7d0df4fe7a0d543c6c9352e7d
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.