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Metathesis of silicon‐containing olefins: IX. Synthesis of 1‐(trimethylsilyl)‐1‐alkenes by olefin metathesis
Authors:
- Zenon Foltynowicz,
- Cezary Pietraszuk,
- Bogdan Marciniec
Abstract
1‐(Trimethylsilyl)‐1‐alkenes of general formula CH3(CH2)nCHCHSi(CH3)3, where n = 3–15, have been prepared by a novel method, viz. by an effective cross‐metathesis of vinyltrimethylsilane with 1‐alkenes catalyzed by RuCl2(PPh3)3. Excess of 1‐alkene in the reaction mixture gave 1‐(trimethylsilyl)‐1‐alkenes in good yields of up to 60% (in terms of vinylsilane). The products were identified by NMR spectroscopic (1H, 13C NMR) and GC MS methods. Copyright © 1993 John Wiley & Sons, Ltd.
- Record ID
- UAMf9b76ff277064bd7bf9e5ee71c8deffa
- Author
- Journal series
- Applied Organometallic Chemistry, ISSN 0268-2605, [1099-0739]
- Issue year
- 1993
- Vol
- 7
- Pages
- 539-541
- ASJC Classification
- ;
- DOI
- DOI:10.1002/aoc.590070714 opening in a new tab
- Language
- en English
- Score (nominal)
- 30
- Score source
- journalList
- Publication indicators
- = 13.000; : 1999 = 1.208; : 2006 = 1.233 (2) - 2007=1.238 (5)
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMf9b76ff277064bd7bf9e5ee71c8deffa/
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or Perishopening in a new tab system.
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