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Molecular Motion in Solid Tetrapropylammonium Bromide and Iodide
Authors:
- Stanisław Lewicki,
- B. Szafrańska,
- Zdzisław Pająk
Abstract
The proton NMR second moment and spin-lattice relaxation time for tetrapropylammonium bromide and iodide have been measured over a wide temperature range. A solid-solid phase transition related to the onset of cation tumbling was found for both salts and confirmed by DTA. In the low temperature phases methyl group reorientation was evidenced. For iodide a dynamic nonequivalence of the methyl groups and the onset of ethyl groups motion was also discovered. © 1992, Verlag der Zeitschrift für Naturforschung. All rights reserved.
- Record ID
- UAMfbfc99ca34524e0882bec89301d6c17b
- Author
- Journal series
- Zeitschrift für Naturforschung. A, A Journal of Physical Sciences, ISSN 0932-0784, e-ISSN 1865-7109
- Issue year
- 1992
- Vol
- 47
- Pages
- 1115-1118
- ASJC Classification
- ; ;
- DOI
- DOI:10.1515/zna-1992-1103 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 9; : 1999 = 0.705; : 2006 (2 years) = 0.904 - 2007 (5 years) =0.807
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMfbfc99ca34524e0882bec89301d6c17b/
- URN
urn:amu-prod:UAMfbfc99ca34524e0882bec89301d6c17b
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.