New organoplatinum (IV) complex with quaterpyridine ligand: Synthesis, structure and its catalytic activity in the hydrosilylation of styrene and terminal alkynes
Authors:
- Ariel Adamski,
- Maciej Kubicki,
- Piotr Pawluć,
- Tomasz Grabarkiewicz,
- Violetta Patroniak
Abstract
The reaction of ligand L with PtCl2 leads to a novel structural motif of octahedral ortho-metalated complex of formula [Pt(L-H) Cl3] 1. This result is a consequence of drastic conditions of reaction and preferred Pt(IV) octahedral coordination geometry. The new compound has been characterised on the basis of the spectroscopic data in solution, and its structure confirmed in the solid state by X-ray crystallography (1a - [Pt(L-H)Cl3]·MeOH, 1b - [Pt(L-H)Cl 3]·C6H5CH3). This article reports organoplatinum (IV) complex 1 as effective and highly selective catalyst precursor in the hydrosilylation of styrene and terminal alkynes. © 2013 Elsevier B.V.
- Record ID
- UAMfc3a718933684131a0c0273fbf52fd1d
- Author
- Journal series
- Catalysis Communications, ISSN 1566-7367
- Issue year
- 2013
- Vol
- 42
- Pages
- 79-83
- ASJC Classification
- ; ;
- DOI
- DOI:10.1016/j.catcom.2013.08.005 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 30
- Score source
- journalList
- Score
- Publication indicators
- = 16; = 19; : 2013 = 1.247; : 2013 (2 years) = 3.320 - 2013 (5 years) =3.366
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMfc3a718933684131a0c0273fbf52fd1d/
- URN
urn:amu-prod:UAMfc3a718933684131a0c0273fbf52fd1d
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.