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Bis(trifluoromethyl)aminyl and bis(trifluoromethyl) nitroxide
Authors:
- Chryssostomos Chatgilialoglu,
- V. Malatesta,
- K.U. Ingold
Abstract
The EPR parameters for (CF3)2N· have been determined to be g = 2.00374, aN = 13.84 G, and aF = 13.84 G in CF2Cl2 from 150 to 220 K. The (CF3)2NO· radical has been generated from (CF3)2Ṅ by using isotopically enriched 17O2. It has a17O equal to 23.6 G which is higher than a17O values found for dialkyl nitroxides (19-20 G). This serves to confirm that (CF3)2NO· has a higher spin density on oxygen than other nitroxides. © 1980 American Chemical Society.
- Record ID
- UAMfdb531dad8504cb9a21649e7fd91a856
- Author
- Journal series
- Journal of Physical Chemistry, ISSN 0022-3654
- Issue year
- 1980
- Vol
- 84
- Pages
- 3597-3599
- ASJC Classification
- ;
- DOI
- DOI:10.1021/j100463a021 Opening in a new tab
- Language
- (en) English
- Score (nominal)
- 0
- Score source
- journalList
- Publication indicators
- = 23; = 25; : 1999 = 2.481
- Citation count
- 33
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- Uniform Resource Identifier
- https://researchportal.amu.edu.pl/info/article/UAMfdb531dad8504cb9a21649e7fd91a856/
- URN
urn:amu-prod:UAMfdb531dad8504cb9a21649e7fd91a856
* presented citation count is obtained through Internet information analysis and it is close to the number calculated by the Publish or PerishOpening in a new tab system.